What is the length of one unit cell in a cubic lattice containing An+ cations and XO₄- anions?

Study for the 2025 QRC Chemist Evaluation Exam. Prepare with flashcards, multiple-choice questions, and detailed explanations. Get exam-ready now!

In a cubic lattice consisting of cations (An+) and anions (XO₄-), the length of the unit cell can be determined by considering the sizes of the ions involved and how they interact geometrically within the lattice structure.

Cubic lattices exhibit a close packing of the constituent ions, typically arranged in such a way that cation and anion radii can be computed to find the lattice parameter or unit cell length. In the case of An+ cations paired with XO₄- anions, their ionic radii play a critical role. The cation radius will generally be smaller than that of the anion due to the difference in charge and the resulting electron cloud size.

The cubic unit cell length can be derived from the effective radii of the An+ cations and XO₄- anions, often leading to the concept of the lattice parameter being influenced by the packing arrangement of these ions. When the ionic radii are known, the unit cell length can then be calculated using established formulas based on the geometry of the lattice structure.

In this context, the most accurate measurement based on the understanding of ionic sizes and their contributions to the overall unit cell dimensions corresponds to 249 picometers (pm). This value

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